Heat treatment
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Heat treatment is a method used to alter the physical, and sometimes chemical, properties of a material. The most common application is metallurgical. Heat treatments are also used in the manufacture of many other materials, such as glass. Heat treatment involves the use of heating or chilling, normally to extreme temperatures, to achieve a desired result such as hardening or softening of a material. Heat treatment techniques include annealing, case hardening, precipitation strengthening, tempering and quenching. It is noteworthy that while the term heat treatment applies only to processes where the heating and cooling are done for the specific purpose of altering properties intentionally, heating and cooling often occur as incidental phases of other manufacturing processes such as hot forming or welding.


Heat treatment of metals and alloys
Metallic materials consist of a microstructure of small crystals called "grains" or crystallites. The nature of the grains (i.e. grain size and composition) determine the overall mechanical behavior of the metal. Heat treatment provides an efficient way to manipulate the properties of the metal by controlling rate of diffusion, and the rate of cooling within the microstructure.

Annealing
Main article: Annealing (metallurgy)
Annealing is a technique used to recover cold work and relax stresses within a metal. Annealing typically results in a soft, ductile metal. When an annealed part is allowed to cool in the furnace, it is called a "full anneal" heat treatment. When an annealed part is removed from the furnace and allowed to cool in air, it is called a "normalizing" heat treatment. During annealing, small grains recrystallize to form larger grains. In precipitation hardening alloys, precipitates dissolve into the matrix, "solutionizing" the alloy.

Hardening and tempering (quenching and tempering)
Main article: Quench
To harden by quenching, a metal (usually steel or cast iron) must be heated into the austenitic crystal phase and then quickly cooled. Depending on the alloy and other considerations (such as concern for maximum hardness vs. cracking and distortion), cooling may be done with forced air or other gas (such as nitrogen), oil, polymer dissolved in water, or brine. Upon being rapidly cooled, the austentite will transform to martensite, a hard brittle crystalline structure.
Untempered martensite, while very hard and strong, is too brittle to be useful for most applications. A method for alleviating this problem is called tempering. Most applications require that quenched parts be tempered (heat treated at a low temperature, often three hundred degree Fahrenheit or one hundred fifty degrees Celsius) to impart some toughness. Higher tempering temperatures (may be up to thirteen hundred degrees Fahrenheit, depending on alloy and application) are sometimes used to impart further ductility, although some strength is lost.
Complex heat treating schedules are often devised by metallurgists to optimize an alloy's mechanical properties. In the aerospace industry, a superalloy may undergo five or more different heat treating operations to develop the desired properties. This can lead to quality problems depending on the accuracy of the furnace's temperature controls and timer.

Precipitation hardening
Main article: Precipitation strengthening
Some metals are considered precipitation hardening metals. Examples include 2000 series, 6000 series, and 7000 series aluminium alloy, as well as some superalloys and some stainless steels. If a precipitation hardened alloy is quenched, its alloying elements will be trapped in solution, resulting in a soft metal. Aging a "solutionized" metal (either at room temperature - "natural aging" - or at a few hundred degrees - "artificial aging") will allow the alloying elements to diffuse through the microstructure and form intermetallic particles. These intermetallic particles will fall out of solution and act as a reinforcing phase, there by increasing the strength of the alloy. In some applications, naturally aging alloys may be stored in a freezer to prevent hardening until after further operations - assembly of rivets, for example, may be easier with a softer part.

Selective hardening
Some techniques allow different areas of a single object to receive different heat treatments. This is called differential hardening. It is common in high quality knives and swords. The Chinese jian is one of the earliest known examples of this, and the Japanese katana the most widely known. The Nepalese Khukuri is another example.

See also
Alloy
Annealing (metallurgy)
Induction heating
Precipitation strengthening
Carbon steel
Tempering
Induction hardening
Carbonitriding